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Maroto, Enrique E. ; Izquierdo, Marta ; Reboredo, Silvia ; Marco-Martínez, Juan ; Filippone, Salvatore ; Martín, Nazario | ACS | 2014Fullerenes are among the most studied molecules during the last three decades, and therefore, a huge number of chemical reactions have been tested on these new carbon allotropes. However, the aim of most of the reactions carried out on fullerene[...]texto impreso
Vidal, Sara ; Izquierdo, Marta ; Alom, Shamim ; García-Borrás, Marc ; Filippone, Salvatore ; Osuna, Silvia ; Solà, Miquel ; Whitby, Richard J. ; Martin León, Nazario | RSC | 2017-10-14The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been [...]texto impreso
Vidal, Sara ; Izquierdo, Marta ; Kit Law, Wai ; Jiang, Kui ; Filippone, Salvatore ; Perles, Josefina ; Yan, He ; Martín, Nazario | RSC | 2016Methanofullerenes such as the well-known [70]PCBM are commonly synthesized under harsh conditions to obtain the product as a mixture of site-isomers (namely a, b and minor c) due to the D5h symmetry of the C70 cage. We report the first site-sele[...]texto impreso
Vidal, Sara ; Izquierdo, Marta ; Filippone, Salvatore ; Brunetti, Fulvio G. ; Martín, Nazario | RSC | 2015The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same tr[...]
