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Muñoz, Antonio ; Illescas, Beatriz M. ; Luczkowiak, Joanna ; Lasala, Fátima ; Ribeiro Viana, Renato ; Rojo, Javier ; Delgado, Rafael ; Martín, Nazario | RSC | 2017-06-12A series of amphiphilic glycodendro[60]fullerene monoadducts were efficiently synthesized using the CuAAC “click chemistry” approach. These glycodendrofullerenes can self?assemble in aqueous media, in a process favoured through ?? [...]texto impreso
Moreira, Luis ; Calbo, Joaquín ; Aragó, Juan ; Illescas, Beatriz M. ; Nierengarten, Iwona ; Delavaux-Nicot, Béatrice ; Ortí, Enrique ; Martín, Nazario ; Nierengarten, Jean-Françoise | ACS | 2016-09Two new conjugated porphyrin-based systems (dimers 3 and 4) endowed with suitable crown ethers have been synthesized as receptors for a fullerene-ammonium salt derivative (1). Association constants in solution have been determined by UVvis titra[...]texto impreso
Ramos, Soriano ; Reina, José J. ; Pérez, Sánchez ; Illescas, Beatriz M. ; Rojo, Javier ; Martín, Nazario | RSC | 2016-07The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent[...]texto impreso
Ramos Soriano, Javier ; Reina, José J. ; Illescas, Beatriz M. ; Rojo, Javier ; Martín, Nazario | ACS | 2018-01-09The synthesis of multivalent systems based on hexakisadducts of [60]fullerene employing a biocompatible copper-free click chemistry strategy has been accomplished. A symmetric hexakis-adduct of fullerene bearing 12 maleimide units (3) is reporte[...]texto impreso
Moreira, Luis ; Calbo, Joaquín ; Illescas, Beatriz M. ; Aragó, Juan ; Nierengarten, Iwona ; Delavaux-Nicot, Béatrice ; Ortí, Enrique ; Martín, Nazario ; Nierengarten, Jean-Françoise | Wiley-VCH | 2015A fullerene-ammonium derivative has been combined with different metalloporphyrin-crown ether receptors to generate very stable supermolecules. The combination of fullerene-porphyrin and ammonium-crown ether interactions leads to a strong chelat[...]texto impreso
The infection of humans by lethal pathogens such as Ebola and other related viruses has not been properly addressed so far. In this context, a relevant question arises: what can chemistry do in the search for new strategies and approaches to sol[...]texto impreso
Muñoz, Antonio ; Sigwalt, David ; Illescas, Beatriz M. ; Luczkowiak, Joana ; Rodríguez, Laura ; Nierengarten, Iwona ; Holler, Michel ; Remy, Jean Serge ; Buffet, Kevin ; Vincent, Stéphane P. ; Rojo, Javier ; Delgado, Rafael ; Nierengarten, Jean-Françoise ; Martín, Nazario | Nature Publishing Group | 2016-01The inhibition of pathogens entry through the blockade of DC-SIGN (dendritic cell-specific intercelular adhesion molecule-3-grabbing nonintegrin) receptor at early stages of infection is an efficient strategy for testing new antiviral agents. Al[...]texto impreso
Moreira, Luis ; Calbo, Joaquín ; Krick Calderón, Rafael M. ; Santos, José ; Illescas, Beatriz M. ; Aragó, Juan ; Nierengarten, Jean-Françoise ; Guldi, Dirk M. ; Ortí, Enrique ; Martín, Nazario | RSC | 2015A series of exTTF-(crown ether)2 receptors, designed to host C60, has been prepared. The size of the crown ether and the nature of the heteroatoms have been systematically changed to fine tune the association constants, which were determined by [...]
